期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 15, 期 -, 页码 208-211出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2011.10.025
关键词
Organic-inorganic hybrid; Hydrothermal method; Sliver; Luminescence
资金
- Chinese Academy of Sciences
- NSF for Young Scientists of China [20801056]
- 973 Program [2011CB932504]
- National Nature Science Foundation of China [20971121]
- Nature Science Foundation of Fujian Province
Treatment of bix (1, 4-bis(imidazole-1-ylmethyl)benzene) with AgI generated [(Ag4I4)(bix)](n) 1, whose crystal structure reveals a 2D organic-inorganic layer formed by novel wave-like silver(I) iodide chains with the linkers of bix ligands. The layers are arranged in parallel with the mode of {ABAB....} type showing ID rectangular channels. In solid state, 1 exhibits multiple emission properties originating from its different natures, while optical absorption spectrum suggests that 1 might be a potential wide-gap semiconductor. (C) 2011 Elsevier B.V. All rights reserved.
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