期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 16, 期 -, 页码 12-16出版社
ELSEVIER
DOI: 10.1016/j.inoche.2011.11.016
关键词
Coordination polymer; Silver(I) compound; Ligand; Crystal structure; Photoluminescence
资金
- Korea Research Foundation (KRF)
- Korean government (MEST) [2009-0073897]
- National Research Foundation of Korea [2009-0073897, 과06B1508] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Silver(I) coordination polymers, [Ag(bpba)(CF3SO3)]center dot 0.5CH(3)CN (1) and [Ag-2(bpba)(2)(NO3)(2)]center dot CH3CN center dot H2O (2) with bis(4-pyridyl)benzylamine (bpba) have been prepared and structurally characterized. 1 shows two-dimensional structure formed by the offset pi-pi stacking interactions between ladder-like chains, whereas 2 displays three-dimensional network linked by one-dimensional chains with 8-shaped. Different from 1, 2 appears a strong visible emission ranging from 450 to 550 nm. (C) 2011 Elsevier B.V. All rights reserved.
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