期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 14, 期 9, 页码 1516-1519出版社
ELSEVIER
DOI: 10.1016/j.inoche.2011.06.011
关键词
Cationic cyclopentadienyliron complex; Synthesis; Photochemistry; Trans/cis isomerization
资金
- national natural science foundation of China [20676012]
Two kinds of cationic cyclopentadienyliron complexes containing arylazo chromophores (Azo-Fc) were synthesized through the nucleophilic aromatic substitution reactions of cyclopentadienyliron chlorobenzene complexes. The synthesized Azo-Fc was characterized by LC-MS, IR, and H-1 NMR. The influence of substituents and the aryl ring on spectral data of the synthesized compounds is described. Unlike other cationic cyclopentadienyliron complexes, Azo-Fc hardly underwent photolysis and showed no photo-initiating abilities in the cationic polymerization under photo-irradiation; in addition, trans/cis isomerization by irradiation is possible at different wavelengths. (C) 2011 Elsevier B.V. All rights reserved.
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