Adjustment of coordination environment of Ln(3+) ions to modulate near-infrared luminescent properties of Ln(3+) complexes

With the Zn-Schiff-base [ZnL(Py)] from the pure Salen-type Schiff-base ligand H2L (H2L = N,N'-bis (salicylidene)ethylene-12-diamine) as the precursor, a series of hetero-trinuclear Zn(2)Ln complexes [Zn(2)Ln (L)(2)(NO3)(2)(SCN)(PY)(2)] (Ln = Nd, 1; Ln = Yb, 2; Ln = Er, 3 and Ln = Gd, 4) are obtained by the further reaction with Ln(NO3)(3)center dot 6H(2)O and KSCN on the condition of stoichiometry control, respectively. The influence of molecular structures on the photophysical properties shows their NIR luminescent properties are hypersensitive to the composition and symmetry of the coordination environments of Ln(3+) ions bonded with the mixed anions, which provides a wide variety of means to modulate the NIR luminescence of Ln(3+) complexes. (C) 2010 Elsevier B.V. All rights reserved.