期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 13, 期 5, 页码 630-632出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2010.03.005
关键词
Organomercury complex; Bipyridine ligand; X-ray structure; Luminescent property
资金
- National Natural Science Foundation of China [20672032, 20572018]
- Specialized Research Funds for Technological Innovative Talent in Harbin [RC2009XK018007]
- University of Heilongjiang
A novel organomercury complex, [Hg-2(mu-CH3COO)(CH3COO)(L)(n)], (L = 1,3-bis(pyridine-2-ylmethoxy) benzene) 1, has been synthesized. Complex 1 has a one-dimensional chain structure formed by acetate anions bridging Hg(II) atoms in crystallographical c-axis. The orthomercuration of the ligand takes place at C-4 and C-6 of benzene ring rather than C-2 position. It shows intense fluorescent emission by solid-state luminescent analysis. (C) 2010 Elsevier B.V. All rights reserved.
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