期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 11, 期 10, 页码 1174-1176出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2008.07.002
关键词
Zirconium; Cyclam; Tetraazamacrocycles; Amido ligands; Ethylene polymerisation; epsilon-Caprolactone polymerisation
资金
- Fundacao para a Ciencia e a Tecnologia, Portugal [POCI/QUI/55744/2004, SFRH/BD/29986/2006]
- Fundação para a Ciência e a Tecnologia [POCI/QUI/55744/2004, SFRH/BD/29986/2006] Funding Source: FCT
The reaction of H-2[1,8-dibenzyl-1,4,8,11-tetraazacyclotetradecanel (H(2)Bn(2)CYclam) with 2 equiv of LiBu gives Li(2)Bn(2)Cyclam(L)2 (L = Et2O or THF) that reacts with ZrCl4(THF)(2) to afford (Bn(2)Cyclam)ZrCl2 in 40% yield. Alternatively (Bn(2)Cyclam)ZrCl2 may be obtained via ZrCl2(CH2SiMe3)(2)(Et2O)(2) in a significantly higher yield (87%), avoiding the lithiation of H(2)Bn(2)Cyclam. The syntheses of other H-2*Bn(2)CYClaM ligand precursors (*Bn = 3,5-dimethylbenzyl and 3,5-di(tert-butyl)benzyl) and the corresponding Zr derivatives ({3,5-Me2Bn}(2)-Cyclam)ZrCl2 and ({3,5-(Bu2Bn)-Bu-t}(2)-Cyclam)ZrCl2 are also reported. Results on preliminary tests of E-caprolactone and ethylene polymerisation reactions are presented. (C) 2008 Elsevier B.V. All rights reserved.
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