期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 11, 期 10, 页码 1132-1135出版社
ELSEVIER
DOI: 10.1016/j.inoche.2008.06.014
关键词
Wells-Dawson polyoxometalate; Flexible ligand; Hydrothermal synthesis; Bis(triazole) ligand
资金
- National Natural Science Foundation of China [20671016]
- Testing Foundation of Northeast Normal University
- Science Foundation for Young Teachers of Northeast Normal University [20070307]
A new Wells-Dawson polyoxometalate-templated compound, (H(3)btb)[Fe(btb)(3)(P2W18O62)] center dot 4H(2)O (1) (btb = 1,4-bis(1,2,4-triazol-1-yl)butane), was synthesized under hydrothermal conditions. Compound 1 presents an interesting zigzag chain (Fe(btb)](infinity)(3+) through using bi-dentate bridging btb ligands, while the mono-dentate pendant btb molecules act as arms hugging the polyanion templates. (C) 2008 Elsevier B.V. All rights reserved.
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