4.7 Article

The influence of the substituents at N1 nitrogen on geometry of nickel(II) complexes with heterocyclic thiosemicarbazones

期刊

INORGANIC CHEMISTRY COMMUNICATIONS
卷 11, 期 9, 页码 972-974

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ELSEVIER
DOI: 10.1016/j.inoche.2008.04.032

关键词

furan-2-carbaldehyde-N-methyl; thiosemicarbazone; thiophene-2-carbaldehyde-N-phenyl; thiosemicarbazone; nickel; square planar complex

资金

  1. CSIR [01(1993)/05/EMR II]

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The influence of the substituents (R) at the N-1 nitrogen of heterocyclic thiosemicarbazones {(C4H3X)-C(H)=N-3-(NH)-H-2-C-1(=S)(NHR)-H-1; X=O, Hftsc; S, Httsc} on the geometry of nickel(II) complexes was investigated. Furan-2-carbaldehyde thiosemicarbazones have formed both trans [Ni(ftsc-N-R)(2)] (R=Me, 1; Et. 2). and cis (R=Ph, 3), square planar complexes unlike thiophene-2-carbaldehyde thiosemicarbazones which yielded only trans square planar complexes [Ni(ttsc-N-R)(2)] (R= Me, 4: Et, S: Ph, 6). (C) 2008 Elsevier B.V. All rights reserved.

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