期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 11, 期 12, 页码 1459-1461出版社
ELSEVIER
DOI: 10.1016/j.inoche.2008.09.022
关键词
Platinum(VI) dihydroxo; Oxidation; Cytochrome P-450; Triphenylphosphine; meta-Chloroperbenzoic acid
资金
- Graduate Study Councils of Shahid Beheshti University
Tetramesitylporphyrin platinum(VI) dihydroxo complex, TMPPt(OH)(2) center dot 2 benzoate was synthesized by addition of two equivalent of meta-chloroperbenzoic acid molecules to the tetramesitylporphyrin platinum(II). This complex was characterized by X-ray diffraction and spectroscopic methods, and is capable to convert two molecules of triphenylphosphine to triphenylphosphine oxide. (c) 2008 Published by Elsevier B.V.
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