期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 11, 期 9, 页码 969-971出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2008.05.009
关键词
coordination polymer; 1H-tetrazole-5-formic acid; crystal structure; diamond-like network
资金
- 973 Program [2006CB932900]
- National Natural Science Foundation of China [20671091, 20425104]
- Fujian Province [A0420002, E0510029]
A tetrazole-based Zn(II) coordination polymer, [Zn(tzf)(2)](n) 1(Htzf= 1H-tetrazole-5-formic acid), was synthesized by reaction of ZnCl2 and Htzf, and structurally characterized by single-crystal X-ray diffraction. Polymer 1 features a 3D-diamond-like net formed by the linkage of Zn(II) atoms and tetrazole groups. The carboxylate O atoms in tzf ligand remain uncoordinated. Polymer 1 displays a second harmonic generation response, which is ca. 1.1 times that of KDP (KH2PO4). The photoluminescent analysis reveals that 1 exhibits strong blue emission resulting from intraligand charge transition. (C) 2008 Elsevier B.V. All rights reserved.
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