期刊
INORGANIC CHEMISTRY
卷 57, 期 20, 页码 12461-12465出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b01922
关键词
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资金
- NSF of China [21871047]
- Innovation Fund Designated for Graduate Students of East China University of Technology [DH YC-201825]
In this work, we designed a hybrid catalyst composed of a metal-organic framework (MOF), Pt nanoparticles (NPs), and ferric oxide, namely, Co-MOF-74@(Pt@Fe2O3), which enables not only high turnover frequencies of up to 245.7 h(-1) but also ultrahigh 100% selectivity toward cinnamyl alcohol in the hydrogenation of cinnamaldehyde under mild conditions. This excellent performance is attributed to the fact that such a hybrid catalyst enables not only strong steric constraint to provide the favored C=O adsorption of cinnamaldehyde but also strong metal-support interaction to lower the electron density of Pt NPs.
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