期刊
INORGANIC CHEMISTRY
卷 57, 期 18, 页码 11482-11491出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b01313
关键词
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资金
- RUDN University Program 5-100
- Ministry of Education and Science of the Russian Federation [RFMEFI61917X0007]
- [17-03-00355]
- [18-03-00228]
- [18-33-00632]
The reaction of Pd-3(OOCMe)(6) with indium(III) and gallium(III) acetates was studied to prepare new Pd-II-based heterometallic carboxylate complexes with group 13 metals. The heterometallic palladium(II)-indium(III) acetate-bridged complexes Pd(OOCMe)(4)In(OOCMe) (1) and Pd(OOCMe)(4)In(OOCMe)center dot MeCOOH (1a) were synthesized and structurally characterized with X-ray crystallography and extended X-ray absorption fine structure in the solid state and solution. A similar Pd-Ga heterometallic complex formed by the reaction of Pd-3(OOCMe)(6) with gallium(III) acetate in a dilute acetic acid solution, as evidenced by atmospheric pressure chemical ionization mass and UV-vis spectrometry, was unstable at higher concentrations and in the solid state. Complex 1 catalyzes the liquid-phase-selective phenylacetylene and styrene hydrogenation (1 atm of H-2 at 20 degrees C) in acetic acid, ethyl acetate, and N,N-dimethylformamide solutions, while no Pd metal was formed until alkyne and alkene hydrogenation ceased.
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