期刊
INORGANIC CHEMISTRY
卷 53, 期 15, 页码 8088-8097出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic5010769
关键词
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资金
- National Natural Science Foundation of China [21073142, 21173168, 21373162]
- Nature Science Foundation of Shanxi Province [SJ08B09, FF10091, 11JS110]
Based on the solvent-induced effect, three new azido-copper coordination polymers-[Cu(2-na)(N-3)] (1), [Cu(2-na)(N-3)] (2), and [Cu(2-na)(N-3)(C2H5OH)] (3) (where 2-na = 2-naphthoic acid)-have been successfully prepared. Structure analysis shows that the Cu(II) cations in compounds 1-3 present tetra-, penta-, and hexa-coordination geometries, respectively. Compound 1 is a well-isolated one-dimensional (ID) chain with the EO-azido group, while 2 is an isomer of 1 and exhibits a two-dimensional (2D) layer involving the EE-azido group. Thermodynamically, density functional theory (DFT) calculation reveals that 2 occupies the stable state and I locates in the metastable state. Compound 3 consists of a ID chain with triple bridging mode, which is derived from 1, and undergoes a single-crystal-to-single-crystal transformation by soaking in ethanol solvent; the powdery product of 1, namely 1b, could be yielded after the dealcoholization of compound 3. Magnetic measurements indicate that compounds 1-3 perform strong intrachain ferromagnetic interactions, experiencing long-range magnetic ordering and slow magnetic relaxation. Compound 1 features the metamagnetic behavior with a transition temperature of 15 K, while 2 and 3 display spin glass behavior with the phase transition temperatures of 15 and 12 K, respectively. Magneto-structure relationships are investigated as well.
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