期刊
INORGANIC CHEMISTRY
卷 53, 期 23, 页码 12590-12594出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic502223n
关键词
-
资金
- NSFC [21431002, 91122007]
- Specialized Research Fund for the Doctoral Program of Higher Education [20110211130002]
A novel water-soluble colorimetric and ratiometric fluorescent probe was synthesized and applied to imaging palladium species under physiological conditions in phosphate buffered saline (PBS) containing less than 1% organic cosolvent without adding any additional reagents. Based on palladium triggered terminal propargyl ethers cleavage reaction, the probe exhibited a high selectivity and sensitivity for palladium species of all the typical oxidation states (0, +2, +4), with a low detection limit (25 nM, 2.7 mu g/L) and an obvious color change. Furthermore, the probe was successfully used for ratiometric fluorescence imaging of palladium in living cells.
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