期刊
INORGANIC CHEMISTRY
卷 53, 期 19, 页码 10024-10026出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic501492c
关键词
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资金
- National Science Foundation of China [21201077, 21171065, 21304092]
- Fundamental Research Funds for the Central Universities [201103099]
Indium metal-organic frameworks (MOFs) were first used as recyclable heterogeneous Lewis acid catalysts for the synthesis of amino acid derivatives with excellent conversion yields. Moreover, exposed ether groups (Lewis basic sites) on the pore walls of In-MOF 2 could activate trimethylsilyl cyanide, forming hypervalent silicate intermediates, as proven by Si-29 NMR.
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