期刊
INORGANIC CHEMISTRY
卷 53, 期 12, 页码 5893-5895出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic500901y
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资金
- NIH [GM101153]
- E2SHI Fellowship
- Solar Technologies Go Hybrid initiative of the State of Bavaria
The reaction of a manganese(V)-oxo porphyrinoid complex with the Lewis acid B(C6F5)(3) leads to reversible stabilization of the valence tautomer Mn-IV(O)(pi-radical cation). The latter complex, in combination with B(C6F5)(3), reacts with ArO-H substrates via formal hydrogen-atom transfer and exhibits dramatically increased reaction rates over the Mn-IV(O) starting material.
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