4.7 Article

Enhancement of Optical Faraday Effect of Nonanuclear Tb(III) Complexes

期刊

INORGANIC CHEMISTRY
卷 53, 期 14, 页码 7635-7641

出版社

AMER CHEMICAL SOC
DOI: 10.1021/ic5009363

关键词

-

资金

  1. Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [2401, 24102012]
  2. Grants-in-Aid for Scientific Research [26810042, 26288030] Funding Source: KAKEN

向作者/读者索取更多资源

The effective magneto optical properties of novel nonanuclear Tb(III) complexes with Tb-O lattice (specifically, [Tb-9(sal-R)(16)(mu-OH)(10)]+NO3-, where sal-R = alkyl salicylate (R = -CH3 (Me), -C2H5 (Et), -C3H7 (Pr), or -C4H9 (Bu)) are reported. The geometrical structures of these nonanudear Tb(III) complexes were characterized using X-ray single-crystal analysis and shape-measure calculation. Optical Faraday rotation was observed in nonanuclear Tb(III) complexes in the visible region. The Verdet constant per Tb(III) ion of the Tb-9(sal-Me) complex is 150 times larger than that of general Tb(III) oxide glass. To understand their large Faraday rotation, electron paramagnetic resonance measurements of Gd(III) complexes were carried out. In this Report, the magneto optical relation to the coordination geometry of Tb ions is discussed.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据