期刊
INORGANIC CHEMISTRY
卷 53, 期 12, 页码 5896-5898出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic500916u
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资金
- IVF [51200545]
- [GACR P207/11/0841]
- [CZ.1.05/2.1.00/03.0058]
- [APVV-00014-11]
- [VEGA 1/0598/14]
- [VVGS-PF-2013-90]
Pseudooctahedral mononuclear cobat(II) complex [Co(abt)(2)(tcm)(2)] (1), where abpt = 4-amino3,5-bis(2-pyridyl)-1,2,4-triazole and tcm = tricyanomethanide anion, shows field-induced slow relaxation of magnetization with U = 86.2 K and large axial and rhombic single-ion zero-field-splitting parameters, D = +48(2) cm(-1) and E/D = 0.27(2) (D = +53.7 cm(-1) and E/D = 0.29 from ab initio CASSCF/NEVPT2 calculations), thus presenting a new example of a field-induced single-ion magnet with transversal magnetic anisotropy.
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