期刊
INORGANIC CHEMISTRY
卷 53, 期 1, 页码 27-29出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic402769u
关键词
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资金
- Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Early Career Research Program of the U.S. Department of Energy [DE-SC0006518]
- University of Pennsylvania
- Research Corporation for Science Advancement (Cottrell Scholar Award)
- NSF [CHE-0840438]
- U.S. National Science Foundation [OCI-1053575]
Oxidation of Ce[N(SiMe3)(2)](3) in the presence of PF6- or BF4- afforded isolation of CeF[N(SiMe3)(2)](3). Structural and electrochemical characterization shows that this compound is in its tetravalent oxidation state and contains a terminal fluoride ligand. Spectroscopy and density functional theory have been used to characterize the Ce-F bond as ionic, which is reinforced by an initial reactivity study that demonstrates the nucleophilicity of the fluoride ligand.
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