期刊
INORGANIC CHEMISTRY
卷 53, 期 1, 页码 21-23出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic4025684
关键词
-
资金
- National Natural Science Foundation of China [21101037, 21272045]
Q[8]-based porous materials were synthesized in the presence of [Md-blockCl4](2-) anions as structure inducers. The driving forces of the structure-directing effect of the [Md-blockCl4](2-) anions may be due to the ion-dipole interaction and hydrogen bonding between the [Md-blockCl4](2-) anions and CH or =CH2 groups on the backs of Q[8] molecules. Moreover, the tests of potential applications show that these porous materials can not only capture organic molecules through the cavity of Q[8] moieties but also adsorb larger organic molecules with different selectivities.
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