期刊
INORGANIC CHEMISTRY
卷 52, 期 8, 页码 4714-4720出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic4003466
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资金
- Centre National de la Recherche Scientifique (CNRS)
- Universite Paul Sabatier (UPS)
- Agence Nationale de la Recherche [ANR-10-BLAN-070901]
Three naphthyl-bridged phosphine-borane derivatives 2-BCy2, 2-BMes(2) and 2-BFlu, differing in the steric and electronic properties of the boryl moiety, have been prepared and characterized by spectroscopic and crystallo-graphic means. The presence and magnitude of the P -> B interactions have been assessed experimentally and theoretically. The naphthyl linker was found to enforce the P -> B interaction despite steric shielding, while retaining enough flexibility to respond to the Lewis acidity of boron.
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