期刊
INORGANIC CHEMISTRY
卷 51, 期 7, 页码 3947-3949出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic3002724
关键词
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资金
- Australian Research Council
Three isostructural hexanuclear lanthanide(III) clusters are reported (Ln(III) = Gd, Tb, and Dy). The metallic core of each complex displays an unusual arrangement of ions, which is stabilized by a mu(6)-carbonate ligand. Magnetic studies show that the Ln(III) ions in each compound are weakly exchange coupled, with the Tb and Dy analogues displaying single-molecule-magnet behavior.
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