期刊
INORGANIC CHEMISTRY
卷 51, 期 3, 页码 1852-1858出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic2021337
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资金
- Chinese Academy of Sciences [KJCX2-EW-209-3, KJCX2-EW-H03-03]
- National Natural Science Foundation of China [50802110, 21001114, 21065012]
- Western Light Joint Scholar Foundation
- Xinjiang Uygur Autonomous Region of China [201116143]
- Natural Science Foundation of Xinjiang Uygur Autonomous Region of China [200821159, 2009211B33]
- Scientific Research Program of Urumqi of China [G09212001]
- Science and Technology in Support of Xinjiang [201091244]
A new noncentrosymmetric polyborate, Ba-2[B6O9(OH)(4)], has been synthesized under a hydrothermal condition. The polyborate contains chiral layers constructed by two kinds of helical chains and also form new B18O42 circles based on B3O8 units [(3: Delta+2T)]. One kind of Ba atom locates in the cavity surrounded by the B11O11 ring within the anion layer, and the other kind of Ba atom inserts between two adjacent layers. UV-vis diffuse reflectance spectroscopy demonstrates that the compound has a cutoff edge below 190 nm and has a large second-harmonic generation (SHG) effect, which is approximately 3 times that of KH2PO4 (KDP) and is type-I phase matchable.
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