High Nuclearity in Azido/Oximate Chemistry: Ni14 and Ni13 Clusters with S=6 and 9 Ground States

In the present work, we report a family of Ni-14 and unprecedented Ni-13 clusters linked by end-on azido and oximato bridges. Ferrimagnetic response gives S = 6 and 9 ground states, resulting in the largest nuclearities and spins in nickel oximato chemistry.