期刊
INORGANIC CHEMISTRY
卷 51, 期 11, 页码 6190-6199出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic300273d
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资金
- Bundesministerium fur Bildung und Forschung (BMBF) [02NUK012B]
- Deutsche Forschungsgemeinschaft [SFB583]
- Cluster of Excellence Engineering of Advanced Materials
- FAU Erlangen-Nuremberg
An inverse trans influence has been observed in a high-valent U(V) imide complex, [(((ArO)-Ar-Ad)(3)N)U(NMes)]. A thorough theoretical evaluation has been employed in order to corroborate the ITI in this unusual complex. Computations on the target complex, [(((ArO)-Ar-Ad)(3)N)U(NMes)], and the model complexes [(((ArO)-Ar-Me)(3)N)U(NMes)] and [(NMe3)(OMe2)(OMe)(3)U(NPh)] are discussed along with synthetic details and supporting spectroscopic data. Additionally, the syntheses and full characterization data of the related U(V) trimethylsilylimide complex [(((ArO)-Ar-Ad)(3)N)U(NTMS)] and U(IV) azide complex [(((ArO)-Ar-Ad)(3)N)U(N-3)] are also presented for comparison.
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