期刊
INORGANIC CHEMISTRY
卷 51, 期 17, 页码 9165-9167出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic301518g
关键词
-
资金
- U.S. Department of Energy, Office of Science [DE-AC52-06NA25396]
The reaction of plutonium(IV) in aqueous nitric acid with tetra-n-butylammonium nitrate leads to the immediate precipitation of [N(n-Bu)(4)](2)[Pu(NO3)(6)] (1) in high yield. The analogous reaction in HCl with tetra-n-butylammonium chloride gives [N(n-Bu)(4)](3)[PuCl6] (2). Both 1 and 2 are soluble in a range of organic solvents and have been characterized by single-crystal X-ray diffraction, IR spectroscopy, and solid- and solution-phase vis-near-IR spectroscopy. 1 and 2 provide facile synthetic entry routes to study plutonium(IV) ligand complexation reactions in organic solvent media under both air/moisture-stable and -sensitive conditions.
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