期刊
INORGANIC CHEMISTRY
卷 51, 期 3, 页码 1933-1942出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic202265u
关键词
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资金
- NSFC [20931006, U0934003, 91122006]
- MSTC [2007CB815304]
- NSF of Fujian Province [2011J01065]
The preparation, characterization, and photochromic properties of a mononuclear gold(I) complex (100) with two identical DTE-acetylides and a dinuclear gold(I) complex (2000) with both DTE-acetylide and DTE-diphosphine are described. Both gold(I) complexes exhibit multistep and multiple photocyclization/cycloreversion reactions. Particularly, four-state and four-color photochromic switch is successfully achieved for the dinuclear gold(I) complex upon irradiation with appropriate wavelengths of light. In contrast, fully ring-closed form is unattained through multiple photocyclization for the two corresponding model organic compounds coupling with the same DTE units as gold(I) complexes but without gold(I)-participation. It is demonstrated that coordination of gold(I) ion to DTE-acetylides exerts indeed a crucial role in achieving stepwise and selective photocydization and cycloreversion reactions for both gold(I) complexes, in which the coordinated gold(I) atom acts as an effective barrier to prohibit intramolecular energy transfer between multi-DTE moieties.
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