期刊
INORGANIC CHEMISTRY
卷 50, 期 20, 页码 9942-9947出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic2009094
关键词
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资金
- JST
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Kansai Research Foundation for Technology Promotion (KRF)
- Japan Society for the Promotion of Science (JSPS)
- Grants-in-Aid for Scientific Research [23550057] Funding Source: KAKEN
Two novel heterotetranuclear complexes [V2O2-(mu-MeO)(2)(mu-WO4)(2)(4,4'-(t)Bubpy)(2)] (1) and [V2O2(mu-MeO)(2)(mu-MoO4)(2)(4,4'-(t)Bubpy)(2)] (2) were synthesized, and the solid state structures of these complexes were revealed by single crystal X-ray crystallography. The heterotetranudear complexes 1 and 2 are centrosymmetric building blocks, considered as consisting of two [VO(4,4'-tubpy)](3+) units bridged mu-MO42- (M = W or Mo) anions connected with methoxy groups. Furthermore, catalytic activities of 1 and 2 in the alcohol oxidation with hydrogen peroxide as terminal oxidants in water as solvent were investigated.
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