期刊
INORGANIC CHEMISTRY
卷 51, 期 1, 页码 10-12出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic201750y
关键词
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资金
- FCT, Portugal [SFRH/BD/44295/2008, PTDC/QUI/66187/2006, PEst-OE/QUI/UI0100/2011]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/44295/2008] Funding Source: FCT
The insertion of isocyanates in (Bn(2)Cyclam)ZrX2 is regioselective; (Bn(2)Cyclam)Zr(OR)(2) produces urea-like moieties by the insertion of RN=C=O in the Zr-N-amido bonds of the cyclam ring. Depending on the bulkiness of the isocyanate R groups, O- and N-bound ureates are formed. (Bn(2)Cyclam)Zr((NHBu)-Bu-t)(2) reacts with MesN=C=O at the terminal Zr-N bonds.
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