期刊
INORGANIC CHEMISTRY
卷 50, 期 11, 页码 5249-5257出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic200580z
关键词
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资金
- Swiss National Science Foundation [200021_119663]
- NANOKAT
- Swiss National Science Foundation (SNF) [200021_119663] Funding Source: Swiss National Science Foundation (SNF)
A series of Fe complexes were synthesized and characterized as small molecule mimics for the active site of [Fe]-hydrogenase (Hmd). The collection includes both structurally new compounds and analogues of previously reported models. These complexes contain the essential ligands of the enzyme, namely, acyl, CO, pyridone, and sulfur ligands. They serve as IR and Mossbauer spectroscopic models for the Fe center in [Fe]-hydrogenase. The field-dependent Mossbauer study of representative model complexes shows that the sign and absolute value of the quadrupole splitting are sensitive to the change in the ligand environment of the Fe center.
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