期刊
INORGANIC CHEMISTRY
卷 50, 期 21, 页码 10528-10530出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic201744n
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资金
- U.S. Department of Energy (DOE) [DE-SC0001015, DE-FC36-07GO17033, DE-AR0000073]
- National Science Foundation [NSF/CBET-0930079]
- Welch Foundation [A-1725]
- NSF/DOE [NSF/CHE-0822838]
- U.S. DOE, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
A (3,24)-connected mesoporous metal organic framework, PCN-69, was synthesized by linking a hexatopic ligand btti with dicopper paddlewheel clusters. This material has rigid connectivity but a flexible framework, which has been attributed to a curvature change of the ligand.
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