期刊
INORGANIC CHEMISTRY
卷 50, 期 12, 页码 5318-5320出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic200295h
关键词
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资金
- NSF of China [21073158, J0830413]
- Zhejiang Provincial Natural Science Foundation of China [Z4100038]
- Fundamental Research Funds for the Central Universities [2010QNA3013]
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20090101110017]
A functional tin(IV)-porphyrin derivative was used as a building block to construct a novel 3D porous metal-organic framework (MOF). The MOF is built up from tin(IV)-porphjrin struts linking up Zn atoms and formates joining Sn-IV centers. The immobilization of the photoactive Sn-porphyrins in the channel walls lets the MOF present remarkable photocatalytic activities for the oxygenation of phenol and sulfides, resulting in excellent yields and remarkable selectivity in heterogeneous phases.
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