期刊
INORGANIC CHEMISTRY
卷 50, 期 17, 页码 8384-8391出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic200943s
关键词
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资金
- Royal Society of Edinburgh
- Marie Curie Actions
- Royal Society
- Wolfson Foundation
- Engineering and Physical Sciences Research Council [EP/F016360/1, EP/F030509/1] Funding Source: researchfish
- EPSRC [EP/F016360/1, EP/F030509/1] Funding Source: UKRI
Vanadate(V)-templated Dawson-type capsules {(VM17VI)-M-IV(VO4)(2)} (M = Mo, W; 1-2) have been synthesized and investigated by electrochemical methods in aqueous and organic media using spectroscopic techniques, EPR, UV-vis/NIR, IR, and CSI-MS (cryospray ionization mass spec.), and the clusters have been examined in the solid state by magnetic studies. The collision-induced dissociation (CID-MS) studies confirmed the solution structures as well as helped pinpoint the position of the vanadium ion on the {VM17}-type shell, which was corroborated by EPR and theoretical studies.
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