期刊
INORGANIC CHEMISTRY
卷 50, 期 21, 页码 10709-10717出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic201173j
关键词
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资金
- Department of Chemistry and Chemical Biology at Cornell University
- National Council of Science and technology in Mexico (CONACyT)
- NIH [GM065313]
- DOE
- BER
- NIH
- NCRR
- BMTP
Iron valence-to-core Fe K beta X-ray emission spectroscopy (V2C XES) is established as a means to identify light atoms (C, N, O) within complex multimetallic frameworks. The ability to distinguish light atoms, particularly in the presence of heavier atoms, is a well-known limitation of both crystallography and EXAFS. Using the sensitivity of V2C XES to the ionization potential of the bound ligand, energetic shifts of similar to 10 eV in the ligand 2s ionization energies of bound C, N, and O may be observed. As V2C XES is a high-energy X-ray method, it is readily applicable to samples in any physical form. This method thus has great potential for application to multimetallic inorganic frameworks involved in both small molecule storage and activation.
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