期刊
INORGANIC CHEMISTRY
卷 50, 期 6, 页码 2079-2081出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic200064n
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资金
- U.S. Department of Energy [DE-SC0002215]
- Deutsche Forschungsgemeinschaft [DE 412/43-1]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001089]
The first plutonium(III) borate, Pu-2[B12O18(OH)(4)Br-2(H2O)(3)]center dot 0.5H(2)O, has been prepared by reacting plutonium(III) with molten boric add under strictly anaerobic conditions. This compound contains a three-dimensional polyborate network with triangular holes that house the plutonium(III) sites. The plutonium sites in this compound are 9- and 10-coordinate and display atypical geometries.
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