期刊
INORGANIC CHEMISTRY
卷 50, 期 22, 页码 11736-11745出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic201745y
关键词
-
资金
- Council of Scientific and Industrial Research, New Delhi, India
- Department of Science and Technology (DST), India
A dinuclear organometallic acceptor 4,4'-bis[trans-Pt(PEt3)(2)(O3SCF3)(ethynyl)]biphenyl (1) containing Pt-ethynyl functionality is synthesized. Multinuclear NMR (H-1, P-31, and C-13), infrared (IR), and electrospray ionization mass spectrometry (ESI-MS) including single-crystal X-ray diffraction analysis established the formation of 1. Equimolar treatment of acceptor 1 separately with three different clip type ditopic donors (L-a-L-c) yielded [2 + 2] self-assembled three metallamacrocycles 2a-2c, respectively. These macrocycles were characterized by various spectroscopic techniques, and their sizes/shapes were obtained through geometry optimization using molecular mechanics universal force field (MMUFF) simulations. Attachment of unsaturated ethynyl functionality to biphenyl building unit helped to make the macrocycles (2a-2c) pi-electron rich and thereby fluorescent in nature. Furthermore, 2c in solution has been examined to be suitable for sensing electron-deficient nitroaromatic like picric acid, which is often considered as a secondary chemical explosive. The fluorescence study of 2c showed a marked quenching of initial emission intensity upon titrating with picric acid (PA), and it exhibited the largest fluorescence quenching response with high selectivity among various other electron deficient aromatic compounds tested.
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