期刊
INORGANIC CHEMISTRY
卷 50, 期 20, 页码 10379-10386出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic201451x
关键词
-
资金
- German Science Foundation [DFG-KO-2288/9-1, DFG-IZ-60/1-1]
- Jacobs University
We have prepared the three novel Pd-II-containing tungstophosphates [Pd-2(alpha-PW11O39H0.5)(2)](9-) and two structural isomers of [Pd-2(alpha-P2W17O61Hn)(2)]((16-2n)-) via simple synthetic procedures and characterized their potassium salts by single-crystal X-ray diffraction, elemental analysis, and IR and multinuclear (P-31 and W-183) NMR spectroscopy. This study sheds light on the long-standing question about the nature and structure of the actual products formed in the reaction of Pd-II ions with monolacunary Keggin-type [alpha-XW11O39](n-) and Wells-Dawson-type [alpha(2)-P2W17O61](10-) heteropolytungstates.
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