期刊
INORGANIC CHEMISTRY
卷 50, 期 15, 页码 7059-7065出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic200566y
关键词
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资金
- NNSF of China [21072049, 50903028]
- Educational Committee of Heilongjiang Province [10td03, 11551336]
- Heilongjiang University [QL201021 and Hdtd2010-08]
- NSERC
- CFI
The syntheses, structures, and magnetic properties are reported for four new lanthanide clusters [Sm-4(mu 3OH)(2)L-2(acac)(6)] center dot 4H(2)O (1), [Gd-4(mu(3)-OH)(2)L-2(acac)(6)]center dot 4CH(3)CN (2), and [Ln(4)(mu(3)-OH)(2)L-2(acac)(6)]center dot 2H(2)L center dot 2CH(3)CN (3, Ln = Tb; 4, Ln = Dy) supported by salen-type (H2L = N,N'-bis(salicylidene)-1,2-cyclohexanediamine) and beta-diketonate (acac = acetylacetonate) ligands. The four clusters were confirmed to be essentially isomorphous by infrared spectroscopy and single-crystal X-ray diffraction. Their crystal structures reveal that the salen-type ligand provides a suitable tetradentate coordination pocket (N2O2) to encapsulate lanthanide(III) ions. Moreover, the planar Ln(4) core is bridged by two mu(3)-hydroxide, four phenoxide, and two ketonate oxygen atoms. Magnetic properties of all four compounds have been investigated using dc and ac susceptibility measurements. For 4, the static and dynamic data indicate that the Dy-4 complex exhibits slow relaxation of the magnetization below 5 K associated with single-molecule magnet behavior.
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