期刊
INORGANIC CHEMISTRY
卷 49, 期 21, 页码 10174-10182出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic101451y
关键词
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资金
- National Natural Science Foundation of China [20772059, 20972073]
- Tianjin Natural Science Foundation [09JCZDJC27900]
Three series of new Ni/Fe/S cluster complexes have been prepared and structurally characterized. One series of such complexes includes the linear type of (diphosphine)Ni-bridged double-butterfly Fe/S complexes [(mu-RS)(mu-S=CS)Fe(2)-(CO)(6)](2)[Ni(diphosphine)] (1-6; R = Et, t-Bu, n-Bu, Ph; diphosphine = dppv, dppe, dppb), which were prepared by reactions of monoanions [(mu-RS)(mu-CO)Fe(2)(CO)(6)](-) (generated in situ from Fe(3)(CO)(12), Et(3)N, and RSH) with excess CS(2), followed by treatment of the resulting monoanions [(mu-RS)(mu-S=CS)Fe(2)(CO)(6)](-) with (diphosphine)NiCl(2). The second series consists of the macrocyclic type of (diphosphine)Ni-bridged double-butterfly Fe/S complexes [mu-S(CH(2))(4)S-mu][(mu-S=CS)Fe(2)(CO)(6)](2)[Ni(diphosphine)] (7-9; diphosphine = dppv, dppe, dppb), which were produced by the reaction of dianion [{mu-S(CH(2))(4)S-mu}{(mu-CO)Fe(2)(CO)(6)}(2)](2-) (formed in situ from Fe(3)(CO)(12), Et(3)N, and dithiol HS(CH(2))(4)SH with excess CS(2), followed by treatment of the resulting dianion [{mu-S(CH(2))(4)S-mu}{(mu-S=CS)Fe(2)-(CO)(6)}(2)](2-) with (diphosphine)NiCl(2). However, more interestingly, when dithiol HS(CH(2))(4)SH (used for the production of 7-9) was replaced by HS(CH(2))(3)SH (a dithiol with a shorter carbon chain), the sequential reactions afforded another type of macrocyclic Ni/Fe/S complex, namely, the (diphosphine)Ni-bridged quadruple-butterfly Fe/S complexes [{mu-S(CH(2))(3)S-mu} {(mu-S=CS)Fe(2)(CO)(6)}(2)](2)[Ni(diphosphine)](2) (10-12; diphosphine = dppv, dppe, dppb). While a possible pathway for the production of the two types of novel metallomacrocycles 7-12 is suggested, all of the new complexes 1-12 were characterized by elemental analysis and spectroscopy and some of them by X-ray crystallography.
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