期刊
INORGANIC CHEMISTRY
卷 49, 期 18, 页码 8347-8350出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic100857y
关键词
-
资金
- Institute of Chemistry, Chinese Academy of Sciences
A new cyclometalating bridging ligand 1,3,6,8-tetra(2-pyridyl)pyrene was designed and synthesized through 4-fold Suzuki couplings between 1,3,6,8-tetrabromopyrene and 2-pyridylboronate. A bis-cyclometalated bisruthenium complex bridged by this ligand showed the presence of an electronic coupling between individual metal centers, as indicated by electrochemical and spectroscopic studies.
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