期刊
INORGANIC CHEMISTRY
卷 49, 期 22, 页码 10680-10686出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic101708y
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资金
- Tokai University
Aerobic oxygenation of diaryl tellurides under photosensitized conditions is investigated. Unlike Ph2S and Ph2Se, reaction of diaryl tellurides with singlet oxygen proceeds smoothly to yield diaryl telluroxides and the corresponding tellurones. The product distribution is largely affected by the substrate and the reaction conditions. In particular, the photooxygenation of bulky diaryl tellurides principally produces tellurones. The results of a series of trapping experiments suggest that the diaryl telluroxides can capture transient intermediates such as Me2S+OO- and Ar2Te+OO-, generated in the singlet oxygen oxidation of chalcogenides, to yield diaryl tellurones, and therefore it may be the most potent precursors of the tellurones.
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