期刊
INORGANIC CHEMISTRY
卷 48, 期 7, 页码 2873-2879出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic801840g
关键词
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资金
- National Nature Science Foundation of China [20571074]
- Nature Science Foundation of Fujian Province [2007J0172]
- [2006CB932900]
Three d(10)-d(10) transition-metal complexes with organosulfur ligands, Cu-6(btt)(6) (1), Cu-4(btt)(4) (2), and Ag-6(bmt)(6) center dot 6THF (3) (Hbtt = 2-benzothiazolethiol, Hbmt = 2-benzimidazolethiol, and THF = tetrahydrofuran), were synthesized and characterized. Complexes 1 and 2 with similar coordination environments are isomers crystallized from the same solvothermal reactions, but they cause great differences in both the structures and luminescent behaviors. The hexanuclear cluster 1 exhibits unusual near-infrared luminescence and high thermal stability, while complex 2 with tetranuclear cores and stronger metal-metal bonds shows an intense red emission like that from complex 3.
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