期刊
INORGANIC CHEMISTRY
卷 48, 期 15, 页码 7080-7085出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic802272q
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资金
- NSF/NIRT [CHE-0403806]
- NSF/CCI [0847926]
- Cornell Center for Materials Research (CCMR)
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0847926] Funding Source: National Science Foundation
Designed prototype molecules for making a three-terminal single-molecule device, star-shaped Fe-II, Co-II, and Ru-II trisbipyridine complexes containing three dithienylcyclopentenes, have been synthesized and characterized. All complexes displayed reversible photochromic behavior when irradiated with UV or visible light. The open form of these complexes could be cyclized electrochemically as revealed by cyclic voltammetric studies and bulk electrolysis experiments.
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