期刊
INORGANIC CHEMISTRY
卷 48, 期 21, 页码 9992-9994出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic901653y
关键词
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资金
- 973 Program of China [2007CBS15302, 2009CB939803]
- The Chinese Academy of Sciences [KJCX2.YW.319, KJCX2.YW.M10]
- Knowledge Innovation Program of the Chinese Academy of Sciences
- Fund of Fujian Key Laboratory of Nanomaterials [2006L2005]
Three isomorphous lead(II) complexes with a new {N3SX}-coordinated (X = Cl, Br, I) mode have been synthesized and characterized by X-ray diffraction. The structural analyses reveal that the coordination environment around the center metal is distinctly influenced by the stereochemical 6s(2) lone pair and N-H center dot center dot center dot X hydrogen bonds. Additionally, doubly deprotonated trzS(2-) (HtrzSH = 1,2,4-triazole-3-thiol) generated in situ via deamination and dehydrazination of ahtrzS(-) (ahtrzSH = 4-amino3-hydrazino-5-mercapto-1,2,4-triazole) was first observed in a semiconducting three-dimensional coordination network at higher reaction temperature.
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