期刊
INORGANIC CHEMISTRY
卷 48, 期 1, 页码 5-7出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic801856q
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资金
- Australian Research Council
The treatment of the hydrazine complex cis-[Fe(N2H4)(dmpe)(2)](2+) with base afforded the diazene complex cis-[Fe(N2H2)(dmpe)(2)]. This reaction is reversed by the treatment of the diazene complex with a mild acid, while treatment of the hydrazine complex with a mixture of KOBut and (BuLi)-Li-t afforded the dinitrogen complex [Fe(N-2)(dmpe)(2)].
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