期刊
INORGANIC CHEMISTRY
卷 48, 期 18, 页码 8650-8652出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic900786b
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资金
- Academia Sinica
- National Science Council, Taiwan
A new bulky pyrene-derived elongated cross-shaped organic scaffold was successfully incorporated into a highly porous, non-interpenetrated square-grid copper(II)-organic framework material with the unprecedentedly huge dimensions of 25.5 x 25.5 angstrom(2), while the layer-to-layer NH center dot center dot center dot N interaction leads to a unique hydrogen-bonded 6(4).8(2)-nbo net.
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