期刊
INORGANIC CHEMISTRY
卷 48, 期 16, 页码 7519-7521出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic901073w
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资金
- U.S. DOE [DE-FC36-07GO17033]
- National Science Foundation [CHE-0449634]
- Argonne National Laboratory
- Institutional Research Program
- National Science Foundation/DOE [CHE-0535644]
- U.S. DOE, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0822838] Funding Source: National Science Foundation
A new porous metal-organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m(2)/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.
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