期刊
INORGANIC CHEMISTRY
卷 48, 期 8, 页码 3890-3895出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic802449w
关键词
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资金
- NSFC [20725102, 50772056]
- National Excellent Doctoral Dissertation of P. R. China
- Chinese Ministry of Education
- Fok Ying Tung Education Foundation [111012]
- Nanoscience and Nanotechnology [2006CB932301]
Ultrathin InOOH nanowires with a diameter of similar to 2 nm and a length up to similar to 200 nm have been synthesized by a hydrolysis reaction in a solution system. Their transformations to c-In2O3 nanocrystals and rh-In2O3 nanowires have been investigated. A dissolution-recrystallization (in solution) or size-related decomposition-recrystallization (in air) mechanism is indicated for the former transformation; the size- and surface-determined transformation is proposed for the latter. These results will help to understand and control the phase stability and transformation concerning the nanodimension and surface restrictions, especially for ultrathin nanowires.
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