期刊
INORGANIC CHEMISTRY
卷 48, 期 2, 页码 423-425出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic8020854
关键词
-
资金
- Welch Foundation [Y-1289]
- NSF [CHE-9601771, CHE-0234811]
A linear gold(I) complex featuring a simple, unstrained alkyne has been synthesized using AuCl and 3-hexyne and characterized using X-ray crystallography. Density functional theory calculations show that sigma donation from alkyne -> Au dominates over the Au -> alkyne pi back-donation.
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