期刊
INORGANIC CHEMISTRY
卷 47, 期 7, 页码 2755-2763出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic702150y
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资金
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0749614] Funding Source: National Science Foundation
The synthesis of new hemilabile phosphine ligands and their reaction with [Rh(COE)(2)Cl](2) to form dissymmetric heteroligated tweezer complexes using a halide-induced ligand rearrangement reaction are reported. These complexes can undergo reactions with small-molecule ligands and elemental anions quantitatively in situ, which serve to regulate the porphyrin-porphyrin distances and interactions within the assembly.
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